Highly efficient blue OLEDs based on diphenylaminofluorenylstyrenes end-capped with heterocyclic aromatics |
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Authors: | Suhyun Oh Kum Hee Lee Young Kwan Kim Seung Soo Yoon |
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Affiliation: | 1. Department of Polymer Science and Engineering, Dankook University, Jukjeon-dong, Suji-gu, Yongin-si, Gyeonggi-do, 448-701, Republic of Korea;2. Department of Nanobiomedical Science & WCU Research Center, Dankook University Graduate School, Chungnam 330-714, Republic of Korea |
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Abstract: | In this paper, we have designed four diphenylaminofluorenylstyrene derivatives end-capped with heterocyclic aromatic groups, such as 9-phenylcabazole, 4-dibenzofuran, 2-benzoxazole, 2-quinoxaline, respectively. These materials showed blue to red fluorescence with maximum emission wavelengths of 476–611 nm, respectively, which were dependent on the structural and electronic nature of end-capping groups. To explore the electroluminescent properties of these materials, multilayer OLEDs were fabricated in the following sequence: ITO/DNTPD (40 nm)/NPB (20 nm)/2% doped in MADN (20 nm)/Alq3 (40 nm)/Liq. (1 nm)/Al. Among those, a device exhibited a highly efficient blue emission with the maximum luminance of 14,480 cd/m2 at 9 V, the luminous efficiency of 5.38 cd/A at 20 mA/cm2, power efficiency of 2.77 lm/W at 20 mA/cm2, and CIEx,y coordinates of (0.147, 0.152) at 8 V, respectively. |
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