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Investigation of energy absorption and transfer process of Tb3+ or Eu3+ excited Na3Gd(PO4)2 in the VUV region
Authors:Dan Wang  Yuhua Wang  Junwen He
Affiliation:1. Department of Materials Science, Lanzhou University, Lanzhou 730000, China;2. Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000, China;3. Graduate School, Lanzhou University, Lanzhou 730000, China;1. Marmara University, Faculty of Engineering, Department of Metallurgical and Materials Science Engineering, ?stanbul 34722, Turkey;2. Bartin University, Faculty of Engineering, Department of Environmental Engineering, Bartin 74100, Turkey;1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China;2. Graduate University of the Chinese Academy of Sciences, Beijing 100049, PR China;1. Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, China;2. College of Chemistry, Jilin University, Changchun 130026, China
Abstract:Na3Gd(PO4)2, Na3Gd0.94(PO4)2:0.06Tb3+ and Na3Gd0.94(PO4)2:0.06Eu3+ are prepared by solid-state reaction and their photoluminescence (PL) properties are investigated in the ultraviolet (UV) and vacuum ultraviolet (VUV) region. The obtained results show that Na3Gd0.94(PO4)2:0.06Tb3+ has an efficient emission under 147 nm excitation, but the emission efficiency of Na3Gd0.94(PO4)2:0.06Eu3+ is low under 147 nm excitation. We discuss the energy absorption and transfer process in the VUV region to solve the special phenomenon.
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