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木素磺酸盐在固体颗粒表面的吸附性能
引用本文:邱学青,杨东杰,欧阳新平. 木素磺酸盐在固体颗粒表面的吸附性能[J]. 化工学报, 2003, 54(8): 1155-1159
作者姓名:邱学青  杨东杰  欧阳新平
作者单位:华南理工大学化工学院,广东 广州 510640
基金项目:国家自然科学基金 (No 2 0 1760 16),教育部骨干教师基金(No 2 0 0 0 65)资助项目~~
摘    要:引 言木素磺酸盐是亚硫酸法生产纸浆或纤维浆的副产物 ,来源于可再生资源 ,具有吸附分散性、黏结性、流变性和胶体性质等表面物化特性 ,广泛应用在染料、涂料、石油工业和建筑业等领域 .木素磺酸盐是具有C3~C6 疏水骨架和以磺酸根为主的亲水性基团的阴离子表面活性剂 ,具有强

关 键 词:木素磺酸钙  吸附  分散  
文章编号:0438-1157(2003)08-1155-05
收稿时间:2002-02-28
修稿时间:2002-02-28

ADSORPTION PERFORMANCE OF CALCIUM LIGNOSULFONATES ON SURFACE OF SOLID PARTICLE
QIU Xueqing,YANG Dongjie,OUYANG Xinping. ADSORPTION PERFORMANCE OF CALCIUM LIGNOSULFONATES ON SURFACE OF SOLID PARTICLE[J]. Journal of Chemical Industry and Engineering(China), 2003, 54(8): 1155-1159
Authors:QIU Xueqing  YANG Dongjie  OUYANG Xinping
Abstract:The adsorption and dispersion of calcium lignosulfonates (CLS) of different molecular mass on the surface of TiO 2 particle is studied in this paper There is a competitive sorption between water molecules and CLS on the solid surface Equilibrium isotherm for the sorption of CLS on TiO 2 surface accords with the Langmuir model On the surface of TiO 2,CLS molecules are adsorbed as spheres with the radius equal to or direct proportional to the radius of gyration The repulsion potential energy of CLS on the surface of particle is static repulsion potential energy and space steric potential energy, and static repulsion potential energy decreases and space steric potential energy increases with increasing molecular mass of CLS.
Keywords:calcium lignosulfonates  adsorption   dispersion  
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