Enhancement of oxygen permselectivity of polydimethylsiloxane-b-polycarbonate film by the surface modification with fluorine-containing polymer |
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Authors: | Yuhsuke Kawakami Toshiki Aoki Yuya Yamashita |
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Affiliation: | (1) Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Furo-cho, Chikusaku, 464 Nagoya, Japan |
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Abstract: | Summary Both oxygen permeability coefficient(PO2) and separation factor ( = PO2/PN2) through polydimethylsiloxane-b-polycarbonate(PDMS/PC) film were improved by the addition of small amounts(1.0 wt%) of the fluorine-containing polymer. This improvement was considered to be caused by the selective solubilization of oxygen in the surfaceaccumulated fluorine polymer domain. |
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