| 微波辐射下5-(1-氧基)-2(5H)-呋喃酮的合成 |
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| 引用本文： | 张熊禄,钟平.微波辐射下5-(1-氧基)-2(5H)-呋喃酮的合成[J].化学世界,2003(6). |
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| 作者姓名： | 张熊禄 钟平 |
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| 作者单位： | 赣南师范学院化学系 江西赣州341000
(张熊禄)，赣南师范学院化学系 江西赣州341000(钟平) |
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| 基金项目： | 江西省教委自然科学基金项目 :[2 0 0 2 ] 2 54号 |
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| 摘 要： | 研究在微波辐射条件下 ,以手性助剂天然薄荷醇与 5 -羟基 -2 (5 H ) -呋喃酮反应 ,合成 5 -(1 -氧基 ) -2 (5 H ) -呋喃酮。获得了微波的功率 40 %、反应时间 1 0 0 min、苯为溶剂 ,薄荷醇 /5 -羟基 -2 -(5 H )呋喃酮为 1 /1 .7,产率 78.6%的好结果
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| 关 键 词： | 微波辐射 有机合成 手性助剂天然薄荷醇 |
Synthesis of 5-(1-Menthyloxy)-2(5H)-furanone under Microwave Irradiation |
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| ZHANG Xiong lu,ZHONG Ping.Synthesis of 5-(1-Menthyloxy)-2(5H)-furanone under Microwave Irradiation[J].Chemical World,2003(6). |
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| Authors: | ZHANG Xiong lu ZHONG Ping |
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| Abstract: | The synthesis of 5 (1 menthyloxy) 2(5 H ) furanone with natrual chiral auxiliary menthol and 5 hydroxy 2(5 H ) furanone under microwave irradiation at normal pressure was studied. A yields of 78% was obtained under the microwave power of 40% at a reaction time of 100 minutes and a menthol /5 hydroxy 2(5 H ) furanone ratio of 1/1.7 when using benzene as solvent. |
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| Keywords: | microwave irradiation organic synthesis natura chiral auxiliary menthol |
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