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高炉内兰炭与焦炭之间的交互作用
引用本文:边城,刘燕军,刘迎立,王京彬,罗明锁,佘雪峰.高炉内兰炭与焦炭之间的交互作用[J].有色金属科学与工程,2019,10(5):12-18.
作者姓名:边城  刘燕军  刘迎立  王京彬  罗明锁  佘雪峰
作者单位:北京科技大学钢铁冶金新技术国家重点实验室,北京,100083;德龙钢铁有限公司,河北 邢台,054009
基金项目:国家重点研发计划资助项目2016YFB0601304中国博士后科学基金资助项目2018M641195
摘    要:通过热重分析实验和模拟氧气高炉中炉料反应行为,探究兰炭和焦炭的反应性,以及兰炭和焦炭之间的交互作用.热重实验结果表明,兰炭反应性优于焦炭,兰炭在加热过程中出现2个DTG峰值,第1个峰值是由于兰炭的二次热解,第2个是由于热解和气化耦合反应.在加热到800 ℃之后,兰炭和焦炭之间存在交互作用,并且随着升温速率的增加,交互作用增强.在高炉炉况下,兰炭的加入能够减少焦炭的反应和焦炭粉化程度,降低CO2和H2O气体对焦炭气孔壁的侵蚀作用,降低大孔的生成,从而对焦炭起到保护作用. 

关 键 词:焦炭  兰炭  交互作用  孔径
收稿时间:2019-05-06

Interaction between semi-coke and coke in blast furnace conditions
Affiliation:1.State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China2.Delong Iron and Steel Co., Ltd., Xingtai 054009, China
Abstract:The reactivity of coke and semi-coke and their interaction have been investigated by conducting the thermogravimetric analysis experiment and simulating the burden reaction in oxygen blast furnace. The experiment shows that the reactivity of semi-coke is superior to that of coke. The semi-coke has two DTG peaks during heating: the first one for the secondary pyrolysis of semi-coke and the second for the coupling reaction of pyrolysis and gasification. The interaction between the semi-coke and the coke appears when the furnace burden is heated to 800 ℃, and as the heating rate increases, their interaction becomes stronger. In the blast furnace conditions, semi-coke can reduce the reaction and pulverization of coke and the erosion of its pore wall by CO2 and H2O, which is a good protection for coke. 
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