| 高温气相色谱分析油脂转酯反应 |
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| 引用本文： | 曾建立,王晓东,赵兵,王玉春. 高温气相色谱分析油脂转酯反应[J]. 中国油脂, 2007, 32(7): 66-69 |
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| 作者姓名： | 曾建立 王晓东 赵兵 王玉春 |
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| 作者单位： | 1. 中国科学院过程工程研究所生化工程国家重点实验室,100080,北京市海淀区中关村北二条1号;中国科学院研究生院,100039,北京市
2. 中国科学院过程工程研究所生化工程国家重点实验室,100080,北京市海淀区中关村北二条1号 |
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| 摘 要： | 建立了高温气相色谱分析油脂转酯反应样品中各种脂肪酸甲酯和脂肪酸甘油酯的方法。样品经硅烷化处理后分流进样,使用VF-5HT高温毛细柱,优化后的程序升温使各种脂肪酸甲酯和甘油酯得到良好分离,同时缩短了分析时间;十三酸甲酯和辛酸三甘油酯双内标分别对脂肪酸甲酯和脂肪酸甘油酯定量,提高了分析的准确度。该方法为油脂转酯反应制备生物柴油提供了分析依据。
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| 关 键 词： | 气相色谱 转酯反应,生物柴油 脂肪酸甲酯 脂肪酸甘油酯 |
| 文章编号： | 1003-7969（2007）07-0066-04 |
| 修稿时间： | 2006-09-30 |
Analysis for oils transesterification reaction by high temperature gas chromatography |
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| ZENG Jian-li,WANG Xiao-dong,ZHAO Bing,WANG Yu-chun. Analysis for oils transesterification reaction by high temperature gas chromatography[J]. China Oils and Fats, 2007, 32(7): 66-69 |
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| Authors: | ZENG Jian-li WANG Xiao-dong ZHAO Bing WANG Yu-chun |
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| Affiliation: | 1. State Key Lab. Biochem. Eng., Institute of Process Engineering, Chinese Academy of Sciences, 100080 Beijing, China; 2. Graduate University of Chinese Academy of Sciences, 100039 Beijing, China |
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| Abstract: | A high temperature gas chromatography method was developed for analyzing fatty acid methyl esters(FAMEs)and mono-(MG),di-(DG)and triglycerides(TG)obtained by the transesterification of vegetable oils.Silylated sample was injected in split mode and analyzed with a VF-5HT capillary column.Complete separation of various methyl esters and glycerides was obtained by a programmed temperature.Methyl tridecanoate and glyceryl trioctanoate served as internal standards separately when the quantities of FAMEs and glycerides were determined.The method is suitable for analyzing the conversion process of oil to biodiesel. |
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| Keywords: | gas chromatography transesterification biodiesel fatty acid methyl esters ac-ylglycerols |
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