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苯丙超微胶乳的合成及性能研究
引用本文:张卫英,赖贵贞,肖玉兰,李晓,陈聪龙.苯丙超微胶乳的合成及性能研究[J].涂料工业,2005,35(2):39-42.
作者姓名:张卫英  赖贵贞  肖玉兰  李晓  陈聪龙
作者单位:福州大学化学化工学院,350002
基金项目:福建省教育厅科技计划项目(No.JA03013),福建省科技厅重点项目(No. 2003H025)
摘    要:以苯乙烯、丙烯酸丁酯为单体,丙烯酸及甲基丙烯酸羟乙酯为功能单体,采用“单体两段滴加法 氨碱微化”制备苯丙超微胶乳,通过正交实验考察了单体用量、预加单体量、乳化剂用量及单体滴加速度等对乳胶透光率的影响,初步研究了乳化剂用量及功能性单体丙烯酸/甲基丙烯酸羟乙酯的配比对乳胶透光率及乳胶膜性能的影响。

关 键 词:苯丙  功能性单体  微胶乳  乳胶膜  乳化剂  甲基丙烯酸羟乙酯  性能研究  单体用量  功能单体  合成
文章编号:0253-4312(2005)02-0039-04
修稿时间:2004年8月4日

Synthesis and Performance of Styrene/Acrylic Super Microemulsion
ZHANG Wei-ying,LAI Gui-zhen,XIAO Yu-lan,et al.Synthesis and Performance of Styrene/Acrylic Super Microemulsion[J].Paint & Coatings Industry,2005,35(2):39-42.
Authors:ZHANG Wei-ying  LAI Gui-zhen  XIAO Yu-lan  
Abstract:The title emulsion has been developed based on styrene and butyl acrylate as reactive monomers and acrylic acid and hydroxy ethyl methacrylate as functional monomers by use of "two-step monomer dropping + ammonium soda micronization" process. The influence of amount of monomers, precharged monomers, emulsifiers and dropping rate of monomers on light transmittance of emulsion is investigated by use of orthogonal tests. The influence of amount of emulsifiers, and the ratio of acrylic acid and hydroxy ethyl methacrylate on light transmittance of emulsion and film properties is also discussed.
Keywords:styrene/acrylic emulsion  super microemulsion  ammoniation  hydroxy ethyl methacrylate
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