Experimental and theoretical study on a novel supramolecular complex constructed from benzenetetracarboxylatic acid and 1,2,3,4-tetra(4-pyridlyl)thiophene |
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Authors: | Ling Qiu Wenxin Li Xiaowei Fan Xuehai Ju Guoxian Cao Shineng Luo |
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Affiliation: | aJiangsu Institute of Nuclear Medicine, Key Laboratory of Nuclear Medicine, Ministry of Health, Wuxi 214063, PR China;bInstitute for Computation in Molecular and Material Science, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China |
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Abstract: | Hydrothermal reaction of benzenetetracarboxylatic acid (H4BTC) with 1,2,3,4-tetra(4-pyridlyl)thiophene (TPT) afforded a novel supramolecular complex [(H4BTC))(TPT)]n (1), which was characterized by FT-IR spectroscopy, elemental analysis, luminescence and thermogravimetric analysis. X-ray single-crystal diffraction reveals that 1 exhibits a one-dimensional (1-D) wave-shape chain assembled through strong hydrogen bonds. Density functional theory (DFT) calculations show that the optimized structures closely resemble the experimental structures. The electronic absorption spectrum of the model dimer in its singlet state has been studied by a time-dependent DFT (TD-DFT) calculation and the nature of the molecular orbitals involved in the fluorescent property was verified. |
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Keywords: | Supramolecular complex Crystal structure Fluorescent spectrum DFT and TD-DFT calculation |
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