Kinetics of the reaction of S-carboxymethyl-L-cysteine with palladium(II) chloride |
| |
| Authors: | JM Nedeljkovi? VM Vasi? VV Vukovi? TS Jovanovi? |
| |
| Affiliation: | Institute of Nuclear Sciences Vinca, Belgrade, Yugoslavia. |
| |
| Abstract: | The influence of the acidity and the Cl- concentration on the kinetics of the complex formation between s-carboxymethyl-L-cysteine and Pd(II) chloride was studied with a stopped-flow technique in the pH range from 1.5 to 5.0 at 25 degrees C. The reaction mechanism involving Pd(H2O)4-nCln, LH-, LH2 and LH3+ species was proposed. Fairly good agreement between the computed and experimentally determined rate constants was found. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
