Electrical Conductivity of TiO2-V2O5-P205 Glasses

The dc conductivities (σ) of V₂O₅-P₂O₅ glasses containing up to 30 mol% TiO₂ were measured at T=100° to ∼10°C below the glass-transition temperature. Dielectric constants from 30 to 10⁶ Hz, densities, and the fraction of reduced V ion were measured at room temperature. The conduction mechanism was considered to be small polaron hopping between V ions, as previously reported for V₂O₅-P₂O₅ glass. The temperature dependence of σ was exponential with σ = σ₀ exp(-W/kT ) in the high-temperature range. When part of the P₂O₅ was replaced by TiO_2,σ increased and W decreased. The hopping energy depended on the reciprocal dielectric constant which, in this case, increased with increasing TiO₂ content.