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Influence of the substitution of Sm, Gd, and Dy for La in La0.7Sr0.3MnO3 on its magnetic and electric properties and strengthening effect on room-temperature CMR
Authors:SONG Qixiang  WANG Guiying  YAN Guoqing  MAO Qiang  WANG Wenqi  PENG Zhensheng
Abstract:A series of La0.7-xSmxSr0.3MnO3, La0.7-xGdxSr0.3MnO3, and La0.7-xDyxSr0.3MnO3 (x=0.00, 0.10, 0.20, 0.30) samples were prepared by the solid-state reaction method. The influence of the substitution of Sm, Gd, and Dy for La on the magnetic and electric properties and on the magnetoresistance (MR) was studied through measurements of M-T curves and p-T curves. The results showed that: lattice distortion in-duced by substitution of Sm, Gd, and Dy for La and extra magnetism of substitution had great influence on the magnetic and electric proper-ties of perovskite manganites; substitution of magnetic rare earth element for La was an effective way to change Curie temperature and to strengthen MR in perovskite manganites; and appropriate substitution proportion would generate large MR near room temperature.
Keywords:magnetic and electric properties  colossal magnetoresistance  Curie temperature  substitution of magnetic rare earth element for La  perovskite manganite  rare earths
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