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Synthesis of polyaniline/Ag composite nanospheres through UV rays irradiation method
Authors:Xia Li  Yu Gao  Fuhong Liu  Jian Gong  Lunyu Qu
Affiliation:1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, 130024, PR China;2. Department of Biology Engineering, Jilin Business and Technology College, Changchun, 130062, PR China;1. CNRS, CRPP, UPR 8641, Université de Bordeaux, F-33600 Pessac, France;2. Depart. Eng. Quimica/CQE, Instituto Superior Técnico/UL, Av. Rovisco Pais, 1049-001 Lisboa, Portugal;3. Université de Bordeaux, IMS, Institut Polytechnique de Bordeaux, CNRS, UMR 5218, F-33607 Pessac Cedex, France;4. Orange Labs, rue du Général Leclerc, 92794 Issy Moulineaux, France;5. Université de Bordeaux, CNRS, ISM, UMR 5255, F-33400 Talence, France;1. School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Ave, Singapore 639672, Singapore;2. Beijing National Laboratory for Molecular Sciences, Laboratory of Organic Solids, Institute of chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;3. Jiangsu-Singapore Joint Research Center for Organic/Bio-Electronics & Information Displays and Institute of Advanced Materials (IAM), Nanjing Tech University, Nanjing 211816, PR China;1. Hitit University, Department of Chemical Engineering, 19065 Çorum, Turkey;2. Hacettepe University, Department of Chemistry, Beytepe, 06800 Ankara, Turkey;1. Advanced Polymer Laboratory, Department of Polymer Science & Technology, University of Calcutta, 92 A.P.C. Road, Kolkata 700 009, India;2. Department of Chemical Engineering, Indian Institute of Technology, Roorkee 247667, India
Abstract:In this paper, a novel morphology of polyaniline (PANI)/Ag composite nanospheres was obtained through UV rays irradiation method. The structure and morphology of the product were characterized by Fourier transform infrared (FT-IR) spectrum, X-ray diffraction (XRD) pattern, Scanning electron micrograph (SEM) and Transmission electron microscopy (TEM) images, energy-dispersive X-ray (EDAX) analysis, and electron diffraction (ED), respectively. The results showed that the diameters of the PANI nanospheres and the Ag nanofilaments were 10–60 nm and 2–5 nm, respectively. UV rays played an important role for forming PANI nanospheres underpinned by Ag nanofilaments. A potential formation mechanism of PANI nanospheres underpinned by Ag nanofilaments was investigated.
Keywords:
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