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Nanocrystalline Y3Al5O12:Ce phosphor-based white light-emitting diodes embedded with CdS:Mn/ZnS core/shell quantum dots
Authors:Jong-Uk Kim  Yong-Seog Kim  Heesun Yang
Affiliation:1. Mesoscopic and Multilayers Structures Laboratory, Department of Physics, Faculty of Science, University of Dschang, P.O. Box 479, Dschang, Cameroon;2. Laboratory of Electronics and Signal Processing, Department of Physics, Faculty of Science, University of Dschang, P.O. Box 67, Dschang, Cameroon;1. Center of Materials and Nanotechnologies, Faculty of Chemical Technology, University of Pardubice, Nam. Cs. Legii 565, Pardubice, 53002, Czech Republic;2. Joint Laboratory of Solid State Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentska 84, Pardubice, 53210, Czech Republic;3. Institute of Applied Physics and Mathematics, Faculty of Chemical Technology, University of Pardubice, Studentska 95, Pardubice, 53210, Czech Republic;4. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentska 95, Pardubice, 53210, Czech Republic;1. The State Key Lab of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;2. Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China;3. Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen, Guangdong 518023, China;4. Department of Chemistry, National Taiwan University, Taipei 106, Taiwan;5. Department of Mechanical Engineering and Graduate Institute of Manufacturing Technology, National Taipei University of Technology, Taipei 106, Taiwan;6. Department of Materials Science and Engineering, Hongik University, Seoul 04066, Republic of Korea
Abstract:120 nm-sized yellow emitting Y3Al5O12:Ce (YAG:Ce) nanocrystalline phosphors and 4.5 nm-sized orange emitting CdS:Mn/ZnS core/shell structured quantum dots (QDs) were prepared by a modified polyol and a reverse micelle chemistry, respectively. To compensate a poor color rendering index (CRI) of YAG:Ce nanophosphor-based white light-emitting diodes (LEDs) due to the lack of red spectral component, CdS:Mn/ZnS QDs were blended into YAG:Ce nanophosphors. Blends of nanophosphors and QDs exhibited the prominent spectral evolution with an increasing content of QDs. A hybrid white LED, which combines a blue LED with the blend of nanophosphor and QDs with a weight ratio of 1:1, was demonstrated with an improved CRI value of 85.
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