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Role of pH in the green synthesis of silver nanoparticles
Authors:Manjeet Singh  I. Sinha  R.K. Mandal
Affiliation:1. Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi 221 005, India;2. Department of Metallurgical Engineering, Centre of Advanced Study. Institute of Technology, Banaras Hindu University, Varanasi 221 005, India;1. Faculty of Pharmacy, AIMST University, Semeling, Bedong, Kedah, Malaysia;2. Faculty of Engineering, The University of Nottingham, Semenyih, Selangor, Malaysia;3. Faculty of Pharmacy, Universiti Teknologi MARA, Puncak Alam Campus, Bandar Puncak Alam, Selangor Darul Ehsan, Malaysia;4. Atta-ur-Rahman Institute for Natural Products Discovery (AuRIns), Universiti Teknologi MARA, Puncak Alam Campus, Bandar Puncak Alam, Selangor Darul Ehsan, Malaysia;5. SLT Institute of Pharmaceutical Sciences, Guru Ghasidas University, Bilaspur, India;1. Department of Biotechnology, SGB Amravati University, Amravati 444 602, Maharashtra, India;2. Center of Natural and Human Sciences, Universidade Federal do ABC, Santo André, SP, Brazil;3. Institute of Chemistry, Biological Chemistry Laboratory, Universidade Estadual de Campinas, Campinas, SP, Brazil;1. Biochemistry Division, Department of Chemistry, University of Pune, Pune 411007, India;2. Centre for Sensor Studies, Department of Electronic Science, University of Pune, Pune 411007, India;3. Sungkyunkwan Advanced Institute of Nanotechnology (SAINT) and Department of Physics, Sungkyunkwan University, Suwon 440746, South Korea;1. Department of Botany, University of Azad Jammu and Kashmir (UAJK), Muzaffarabad 13100, Pakistan;2. Department of Chemical Engineering, Pakistan Institute of Engineering and Applied Sciences (PIEAS), Islamabad 45650, Pakistan;1. School of Chemical Engineering and Advanced Materials, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK;2. Department of Chemical Engineering, AISSMS College of Engineering, Next to RTO, Pune 411001, India;3. Chemical Engineering and Process Development Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India;4. Department of Physics, Durham University, South Road, Durham, DH1 3LE, UK
Abstract:The role of pH in the green synthesis of silver nanoparticles (AgNPs) is investigated. For the reduction synthesis of AgNPs we use silver nitrate, glucose, sodium hydroxide and starch respectively to serve as precursor, reducing agent, accelerator and stabilizer. The effect of NaOH addition on the nature of AgNPs is systematically studied. Two reaction pathways are proposed to explain the formation of AgNPs, keeping in view the pH changes that occur on addition of different amounts of NaOH. The aqueous sol of AgNPs prepared at different pH values display different surface plasmon resonance (SPR) behavior. This is explained in terms of size and size distribution of AgNPs.
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