Synthesis and characterization of a novel biodegradable thermoplastic shape memory polymer |
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Authors: | Yuanliang Wang Yonggang Li Yanfeng Luo Meina Huang Zhiqing Liang |
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Affiliation: | 1. Research Center of Bioinspired Material Science and Engineering (BIMSEC) for National 985 Engineering Plan, Bioengineering College of Chongqing University, Chongqing, 400044, China;2. Department of Gynecology and Obstetrics, Southwest Hospital, Third Military Medical University, Chongqing, 400038, China;1. University of Groningen, University Medical Center Groningen, Department of Biomedical Engineering, W.J. Kolff Institute, PO Box 196, 9700 AD Groningen, The Netherlands;2. Department of Clinical Sciences of Companion Animals, Faculty of Veterinary Medicine, Utrecht University, PO Box 80154, 3508 TD Utrecht, The Netherlands;3. Institute of Biomaterial Science, Helmholtz-Zentrum Geesthacht, Kantstrasse 55, 14513 Teltow, Germany;4. MIRA Institute for Biomedical Technology and Technical Medicine, Department of Biomaterials Science and Technology, Faculty of Science and Technology, University of Twente, P.O. Box 217, 7500 AE, Enschede, The Netherlands.;1. Centre for Composite Materials and Structures, Harbin Institute of Technology (HIT), No. 2 YiKuang Street, PO Box 3011, Harbin 150080, People’s Republic of China;2. Department of Astronautical Science and Mechanics, Harbin Institute of Technology (HIT), No. 92 West Dazhi Street, PO Box 301, Harbin 150001, People’s Republic of China;1. Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA;2. Department of Biomedical Engineering, 5045 Emerging Technologies Building, 3120 Texas A&M University, College Station, TX 77843-3120, USA;1. College of Aerospace and Civil Engineering, Harbin Engineering University, Harbin, China;2. School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006, Australia;1. Department of Mechanical Engineering, Tarbiat Modares University, P.O. Box 14115-111, Tehran, Iran;2. School of Mechanical Engineering, College of Engineering, University of Tehran, P.O. Box 515-14395, Tehran, Iran;3. Department of Hematology, School of Medical Sciences, Tarbiat Modarres University, P.O. Box 14115-331, Tehran, Iran;4. Department of Tissue Engineering and Nanotechnology, Stem Cells Technology Research Center, P.O. Box 1997775555, Tehran, Iran |
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Abstract: | A novel poly(urethane-urea) shape memory polymer (PUU SMP) was synthesized from poly(DL-lactic acid) (PDLLA) Diols, hexamethylene diisocyanate(HDI) and butanediamine(BDA), aiming to develop a biodegradable and biocompatible shape memory polymer. Its structure, thermal properties and shape-memory behaviors were characterized through Fourier transform infrared spectrometry (FTIR), differential scanning calorimetry (DSC) and bending test. The results showed that the response temperature for shape memory of PDLLA–PUU SMP is dependent on the polymeric glass transition temperature and this polymer has an excellent shape memory effect, having the ratio of the shape-memory fixation approximately 100% and the ratio of the shape-memory recovery about 98%. |
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