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Electrodeposition of ZnO nanorods in the presence of metal ions
Authors:Bjoern Seipel  Athavan Nadarajah  Ben Wutzke  Rolf Könenkamp
Affiliation:1. Engineering Department, University of Naples “Parthenope”, Centro Direzionale Isola C4-80133, Napoli, Italy;2. University of Rome “Niccolò Cusano”, Via Don Carlo Gnocchi 3-00146, Roma, Italy;3. Enterprise Department, University of Rome “Tor Vergata”, Via del Politecnico 1-00133, Roma, Italy;1. DEIM, University of Tuscia, Largo dell''Università, 01100 Viterbo, Italy;2. Department of Enterprise Engineering, University of Rome “Tor Vergata”, Via del Politecnico 1, 00133 Rome, Italy
Abstract:We report on structural and optical changes induced by impurity incorporation in ZnO nanorods grown via electrodeposition. We find the lattice parameters of the hexagonal ZnO rods to be larger than in defect-free single-crystalline ZnO. SIMS measurements indicate impurity incorporation and doping in the bulk of the nanorods. The impurity content correlates with changes in the electroluminescence spectra. The maximum of the defect luminescence band around 600 nm shifts towards longer wavelengths with metal incorporation. Aluminum incorporation leads to a narrow luminescence band close by the bandgap of ZnO around 390 nm.
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