A pair of nonporous homochiral cobalt-based coordination polymers for enantioselective recognition and electrocatalysis |
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| Affiliation: | 1. Pharmacy College, Henan University of Traditional Chinese Medicine, Zhengzhou, China;2. The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China;1. College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi 830054, China;2. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;3. Institut de Chimie de Strasbourg, CNRS-UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg, France |
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| Abstract: | A pair of nonporous enantiomers Co(H2O)(bpy)(L-Mand)]?H2O?Cl (L-1) and Co(H2O)(bpy)(L-Mand)]?H2O?Cl (D-1) (L-Mand = L-Mandelic acid, D-Mand = D-Mandelic acid, bpy = 4,4′-bipyridine) with 3D supermolecule framework possess excellent enantioselective recognition and electrocatalysis ability towards L- and/or D-tart. |
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