Isomerization-induced introduction of metal cations into polyoxomolybdate-surfactant hybrid crystals |
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| Affiliation: | 1. Department of Chemistry, School of Science, Tokai University, 4-1-1 Kitakaname, Hiratsuka 259-1292, Japan;2. Application Laboratories, Rigaku Corporation, 3-9-12 Matsubara-cho, Akishima 196-8666, Japan;3. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan;1. School of Chemistry and Life Science, Changchun University of Technology, Changchun, Jilin 130012, China;2. Advanced Institute of materials Science, Changchun University Of Technology, Changchun 130012, China;1. Center for Strategic Utilization of Elements, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan;2. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan;3. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, China;4. International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan;5. Global Research Center for Environment and Energy based on Nanomaterials Science (GREEN), Center for Green Research on Energy and Environmental Materials, National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan;1. State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;2. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China |
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| Abstract: | Monovalent metal cations (Ag+, K+, and Cs+) were successfully introduced into inorganic-organic hybrid crystals composed from β-type octamolybdate (β-Mo8) and hexadecylpyridinium (C16py). The introduction of metal cations was induced by the molecular isomerization from α-Mo8 to β-Mo8 anion. All hybrid crystals consisted of alternate stacking of β-Mo8 inorganic and C16py organic layers. In the inorganic layers, the metal cations and β-Mo8 anions were connected to form one- or two-dimensional arrangement, which depended on the ionic radius of metal cations. |
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