A pair of novel 4-connected homochiral coordination polymers based on proline-tetrazole ligand |
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| Affiliation: | 1. Department of Chemistry, Zunyi Normal College, Zunyi, Guizhou 563002, PR China;2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China |
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| Abstract: | A pair of novel 2D homochiral coordination polymers based on proline-tetrazole ligand, namely [Cd((S)-PTZ)2]n (1-L) and [Zn((S)-PTZ)2]n (2-L), were obtained and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, solid-state CD spectra, single-crystal X-ray crystallography and powder X-ray diffraction. The compounds 1-L and 2-L display 4-connected net and SHG response. |
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