Two Cd(II) coordination polymers based on 3,6-bis(imidazol-1-yl)carbazole: Syntheses,structures and photocatalytic properties |
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| Affiliation: | 1. Department of Chemistry, Periyar University, Salem 636 011, Tamilnadu, India;2. Centre for Nanoscience and Nanotechnology, Periyar University, Salem 636 011, Tamilnadu, India;3. Center of Excellence for Research in Engineering Materials (CEREM), Advanced Manufacturing Institute, King Saud University, P.O. Box 800, Al-Riyadh 11421, Saudi Arabia;4. Electrochemistry and Corrosion Laboratory, Department of Physical Chemistry, National Research Centre (NRC), Dokki, 12622 Cairo, Egypt;5. Department of Physics, Periyar University, Salem 636 011, Tamilnadu, India;6. Department of Physics, School of Basic and Applied Sciences, Central University of Tamilnadu, Thiruvarur 610 101, Tamilnadu, India;1. Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, M. C. Skłodowskiej Sq. 2, 20-031 Lublin, Poland;2. Chair and Department of Medical Chemistry, Medical University, 4A Chodźki Street, 20-093 Lublin, Poland;3. Laboratory of Bioorganic Synthesis and Analysis, Chair and Department of Medical Chemistry, Medical University, 4A Chodźki Street, 20-093 Lublin, Poland;1. Department of Pharmaceutical Sciences, University at Buffalo, The State University of New York, Buffalo, New York 14214;2. Department of Medicine, University of North Carolina School of Medicine, Chapel Hill, North Carolina 27516;3. Department of Pathology and Laboratory Medicine, University of North Carolina School of Medicine, Chapel Hill, North Carolina 27516;1. Centro Brasileiro de Pesquisas Físicas (CBPF), Rio de Janeiro, Brazil;2. Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, Brazil;3. Center for High Energy Physics, Tsinghua University, Beijing, China;4. LAPP, Université de Savoie, CNRS/IN2P3, Annecy-Le-Vieux, France;5. Clermont Université, Université Blaise Pascal, CNRS/IN2P3, LPC, Clermont-Ferrand, France;6. CPPM, Aix-Marseille Université, CNRS/IN2P3, Marseille, France;7. LAL, Université Paris-Sud, CNRS/IN2P3, Orsay, France;8. LPNHE, Université Pierre et Marie Curie, Université Paris Diderot, CNRS/IN2P3, Paris, France;9. Fakultät Physik, Technische Universität Dortmund, Dortmund, Germany;10. Max-Planck-Institut für Kernphysik (MPIK), Heidelberg, Germany;11. Physikalisches Institut, Ruprecht-Karls-Universität Heidelberg, Heidelberg, Germany;12. School of Physics, University College Dublin, Dublin, Ireland;13. Sezione INFN di Bari, Bari, Italy;14. Sezione INFN di Bologna, Bologna, Italy;15. Sezione INFN di Cagliari, Cagliari, Italy;16. Sezione INFN di Ferrara, Ferrara, Italy;17. Sezione INFN di Firenze, Firenze, Italy;18. Laboratori Nazionali dell''INFN di Frascati, Frascati, Italy;19. Sezione INFN di Genova, Genova, Italy;20. Sezione INFN di Milano Bicocca, Milano, Italy;21. Sezione INFN di Milano, Milano, Italy;22. Sezione INFN di Padova, Padova, Italy;23. Sezione INFN di Pisa, Pisa, Italy;24. Sezione INFN di Roma Tor Vergata, Roma, Italy;25. Sezione INFN di Roma La Sapienza, Roma, Italy;26. Henryk Niewodniczanski Institute of Nuclear Physics Polish Academy of Sciences, Kraków, Poland;27. AGH – University of Science and Technology, Faculty of Physics and Applied Computer Science, Kraków, Poland;28. National Center for Nuclear Research (NCBJ), Warsaw, Poland;29. Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest-Magurele, Romania;30. Petersburg Nuclear Physics Institute (PNPI), Gatchina, Russia;31. Institute of Theoretical and Experimental Physics (ITEP), Moscow, Russia;32. Institute of Nuclear Physics, Moscow State University (SINP MSU), Moscow, Russia;33. Institute for Nuclear Research of the Russian Academy of Sciences (INR RAN), Moscow, Russia;34. Budker Institute of Nuclear Physics (SB RAS) and Novosibirsk State University, Novosibirsk, Russia;35. Institute for High Energy Physics (IHEP), Protvino, Russia;36. Universitat de Barcelona, Barcelona, Spain;37. Universidad de Santiago de Compostela, Santiago de Compostela, Spain;38. European Organization for Nuclear Research (CERN), Geneva, Switzerland;39. Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, Switzerland;40. Physik-Institut, Universität Zürich, Zürich, Switzerland;41. Nikhef National Institute for Subatomic Physics, Amsterdam, The Netherlands;42. Nikhef National Institute for Subatomic Physics and VU University Amsterdam, Amsterdam, The Netherlands;43. NSC Kharkiv Institute of Physics and Technology (NSC KIPT), Kharkiv, Ukraine;44. Institute for Nuclear Research of the National Academy of Sciences (KINR), Kyiv, Ukraine;45. University of Birmingham, Birmingham, United Kingdom;46. H.H. Wills Physics Laboratory, University of Bristol, Bristol, United Kingdom;47. Cavendish Laboratory, University of Cambridge, Cambridge, United Kingdom;48. Department of Physics, University of Warwick, Coventry, United Kingdom;49. STFC Rutherford Appleton Laboratory, Didcot, United Kingdom;50. School of Physics and Astronomy, University of Edinburgh, Edinburgh, United Kingdom;51. School of Physics and Astronomy, University of Glasgow, Glasgow, United Kingdom;52. Oliver Lodge Laboratory, University of Liverpool, Liverpool, United Kingdom;53. Imperial College London, London, United Kingdom;54. School of Physics and Astronomy, University of Manchester, Manchester, United Kingdom;55. Department of Physics, University of Oxford, Oxford, United Kingdom;56. Massachusetts Institute of Technology, Cambridge, MA, United States;57. University of Cincinnati, Cincinnati, OH, United States;58. University of Maryland, College Park, MD, United States;59. Syracuse University, Syracuse, NY, United States;1. School of Science, Nantong University, Nantong, Jiangsu 226007, China;2. School of Physics, Huazhong University of Science and Technology, Wuhan 430074, China |
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| Abstract: | Hydrothermal reactions of CdCl2·2.5H2O with 3,6-bis(imidazol-1-yl)carbazole (bmcz), 2-amine-1,4-benzenedicarboxylic acid (2-NH2-1,4-H2BDC) or 1,4-naphthalenedicarboxylic acid (1,4-H2NDC) afforded two coordination polymers, Cd(2-NH2-1,4-BDC)(bmcz)]n (1) and Cd(1,4-NDC)(bmcz)]n (2). Complexes 1 and 2 were characterized by elemental analysis, IR, powder X-ray diffraction, and single-crystal X-ray diffraction. 1 and 2 are isomorphic and exhibit 3D supermolecular structures. The solid state luminescent and optical properties of 1 and 2 at ambient temperature were also investigated. A comparative study on their photocatalytic activity toward the degradation of methylene blue in polluted water was explored. |
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