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Nitrogen doped secondary particle graphite anode for high capacity and high rate Li ion battery
Authors:LI Ronghui  YAN Wei  WU Xiaoqiang  FAN Qinna
Affiliation:1 Tianjin Lishen Battery Joint Stock Co. LTD., Tianjin 300384, China;
2 Inner Mongolia University for the Nationalities, Tongliao 028000, Inner Mongolia, China;
3 Shijiazhuang Tiedao University, Shijiazhuang 050043, Hebei, Chian
Abstract:The high specific capacity with high rate characteristic graphite anode was synthesized by nitrogen doping and secondary particle bonding technologies. The reversible capacity of the obtained graphite was 359.8mAh/g. The full pouch cells with the minimal energy density of 230Wh/Kg (650Wh/L) were assembled to evaluate the electrical performance. The charging capacity can research 51% within 10 minutes, and 100% within 30 minutes, demonstrating an excellent fast charging characteristics. The fast charge cycle test with 3C-rate charge and 1C-rate discharge was conducted at room temperature. It shows that even after 1000 cycles, there is still 88% of the initial capacity, and the maximum swelling rate is 10.1%, which can meet the demand of most electron devices and electric vehicles.
Keywords:N doped graphite  secondary particle  fast charge  high specific capacity  
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