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Combustibility and hazard of lithium iron phosphate power battery components in different aging states
Authors:GAO Fei  WANG Kangkang  TIAN Baogui  CHEN Qingtao  YANG Kai  SU Zhenxi  ZHANG Mingjie  LIU Wei  FAN Maosong  LIU Hao  GENG Mengmeng  WANG Kaifeng
Affiliation:1 State Key Laboratory of Operation and Control of Renewable Energy&Storage Systems, China Electric Power Research Institute, Beijing 100192, China;
2 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
3 State Grid Anhui Electric Power CO. LTD, Hefei 230000, Anhui, China
Abstract:In this paper, four kinds of aging states, capacity retention ratio (CRR) of 100%, 85%, 75% and 65% lithium ion phosphate power battery were selected as the research objects. The combustibility and smoke generation of key components of the battery (positive, negative and separator, all containing electrolyte) were studied by cone calorimeter. The fire risk assessment index system of batteries with different aging states was established by using AHP (analytic hierarchy process). The results show that the effective combustion heat value of the negative electrode decreases as the battery CRR declines, And the yield of CO2 and total smoke production of battery components gradually decrease. The normalized risk index of battery components with a capacity retention rate of 100%~85% is significantly higher than that of battery components with a capacity retention rate of 75%~65%.
Keywords:lithium iron phosphate power battery  cone calorimeter  risk assessment  analytic hierarchy process (AHP)  fire hazard index  
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