A Facile Route for Synthesis of LiFePO4/C Cathode Material with Nano-sized Primary Particles |
| |
Authors: | XIAO Zhengwei HU Guorong DUKe PENG Zhongdong |
| |
Affiliation: | 1.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China;2.School of Metallurgy and Environment, Central South University, Changsha 410083, China |
| |
Abstract: | A facile and practical route was introduced to prepare LiFePO4/C cathode material with nano-sized primary particles and excellent electrochemical performance. LiH2PO4 was synthesized by using H3PO4 and LiOH as raw materials. Then, as-prepared LiH2PO4, reduced iron powder and α-D-glucose were ball-milled, dried and sintered to prepare LiFePO4/C. X-ray diffractometry was used to characterize LiH2PO4, ball-milled product and LiFePO4/C. Differential scanning calorimeter-thermo gravimetric analysis was applied to investigate possible reactions in sintering and find suitable temperature for LiFePO4 formation. Scanning electron microscopy was employed for the morphology of LiFePO4/C. As-prepared LiH2PO4 is characterized to be in P21cn(33) space group, which reacts with reduced iron powder to form Li3PO4, Fe3(PO4)2 and H2 in ball-milling and sintering. The appropriate temperature for LiFePO4/C synthesis is 541.3-976.7℃. LiFePO4/C prepared at 700℃ presents nano-sized primary particles forming aggregates. Charge-discharge examination indicates that as-prepared LiFePO4/C displays appreciable discharge capacities of 145 and 131 mA·h·g-1 at 0.1 and 1 C respectively and excellent discharge capacity retention. |
| |
Keywords: | lithium ion cell reduced iron powder ball-milling LiFePO4/C nano-sized primary particle |
本文献已被 CNKI 维普 ScienceDirect 等数据库收录! |
| 点击此处可从《中国化学工程学报》浏览原始摘要信息 |
|
点击此处可从《中国化学工程学报》下载全文 |
|