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滑动弧放电等离子体法用于二甲醚重整制氢
引用本文:王保伟,孙启梅,吕一军,杨美琳,闫文娟.滑动弧放电等离子体法用于二甲醚重整制氢[J].中国化学工程学报,2014,22(1):104-112.
作者姓名:王保伟  孙启梅  吕一军  杨美琳  闫文娟
作者单位:Key Laboratory for Green Chemical Technology, School of Chemical Engineering Technology, Tianjin University, Tianjin 300072, China
基金项目:Supported by the National Natural Science Foundation of China (21176175, 20606023).
摘    要:Gliding arc gas discharge plasma was used for the generation of hydrogen from steam reforming of dimethyl ether (DME). A systemic procedure was employed to determine the suitable experimental conditions. It was found that DME conversion first increased up to the maximum and then decreased slightly with the increase of added water and air. The increase of total feed gas flow rate resulted in the decrease of DME conversion and hydrogen yield, but hydrogen energy consumption dropped down to the lowest as total feed gas flow rate increased to 76 ml. min^-1. Larger electrode gap and higher discharge voltage were advantageous. Electrode shape had an important effect on the conversion of DME and production of H2- Among the five electrodes, electrode 2# with valid length of 55 mm and the radian of 34 degrees of the top electrode section was the best option, which enhanced obviously the conversion of DME.

关 键 词:dimethyl  ether  steam  reforming  hydrogen  production  gliding  arc  gas  discharge  
收稿时间:2012-04-16

Steam Reforming of Dimethyl Ether by Gliding Arc Gas Discharge Plasma for Hydrogen Production
WANG Baowei,SUN Qimei,LU Yijun,YANG Meilin and YAN Wenjuan.Steam Reforming of Dimethyl Ether by Gliding Arc Gas Discharge Plasma for Hydrogen Production[J].Chinese Journal of Chemical Engineering,2014,22(1):104-112.
Authors:WANG Baowei  SUN Qimei  LU Yijun  YANG Meilin and YAN Wenjuan
Affiliation:Key Laboratory for Green Chemical Technology, School of Chemical Engineering Technology, Tianjin University, Tianjin 300072, China
Abstract:Gliding arc gas discharge plasma was used for the generation of hydrogen from steam reforming of dimethyl ether (DME). A systemic procedure was employed to determine the suitable experimental conditions. It was found that DME conversion first increased up to the maximum and then decreased slightly with the increase of added water and air. The increase of total feed gas flow rate resulted in the decrease of DME conversion and hydrogen yield, but hydrogen energy consumption dropped down to the lowest as total feed gas flow rate increased to 76 ml·min-1. Larger electrode gap and higher discharge voltage were advantageous. Electrode shape had an important effect on the conversion of DME and production of H2. Among the five electrodes, electrode 2# with valid length of 55 mm and the radian of 34 degrees of the top electrode section was the best option, which enhanced obviously the conversion of DME.
Keywords:dimethyl ether  steam reforming  hydrogen production  gliding arc gas discharge
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