有机膨润土改性高吸油树脂的制备与性能研究 |
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引用本文: | 王洁;商平.有机膨润土改性高吸油树脂的制备与性能研究[J].中国塑料,2009,23(11):48-52. |
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作者姓名: | 王洁;商平 |
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作者单位: | 天津科技大学 |
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摘 要: | 对膨润土进行了预处理,然后使用十六烷基三甲基溴化铵(HDTMAoBr)对其进行有机化改性,最后将有机膨润土加入到丙烯酸酯有机单体、交联剂、引发剂的混合液中聚合制得复合高吸油树脂。结果表明,加入单体总质量1.5 %的膨润土所得的树脂最大吸油可达14.1 g/g。通过正交实验讨论了最佳工艺条件。有机膨润土与丙烯酸酯吸油树脂具有良好的相容性,与未添加膨润土的树脂相比,复合树脂吸油性能、热分解温度均有提高。
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关 键 词: | 有机膨润土 正交试验 制备 吸油树脂 |
收稿时间: | 2009-8-27 |
Preparation and Properties of Organic Bentonite Compound High Oil Absorption Resin |
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Abstract: | Bentonite was pre-treated and organically modified with HDTMAoBr, which was introduced into a polymerization system of acrylate monomer, crosslinker, and initiator resulting in a high oil-absorbing resin. The addition of 1.5wt % of the modified bentonite led to an oil-absorbing degree of 14.1 g/g. The optimal recipe was obtained via orthogonal experiments. The organic bentonite was well compatible with the acrylate resin, the thermal stability of the latter was improved. |
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Keywords: | organic bentonite orthogonal test preparation oil-absorbing resin |
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