Design and Properties of New Functional Water – Soluble Polymers of Citraconic Anhydride (CA) and Related Copolymers |
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| Authors: | Murat Barsbay Hatice Kaplan Can Zakir M.O. Rzaev Ali Güner |
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| Affiliation: | (1) Department of Chemistry, Faculty of Science, Hacettepe University, Beytepe, 06532 Ankara, Turkey;(2) Department of Chemical Engineering, Faculty of Engineering, Hacettepe University, Beytepe, 06532 Ankara, Turkey |
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| Abstract: | Summary The binary and ternary copolymers are synthesized by free-radical initiated binary copolymerization of citraconic anhydride (CA) with acrylamide (AAm) and terpolymerization of acrylamide (AAm) – citraconic anhydride (CA) – vinyl acetate (VA) monomer system. Co- and terpolymerization were carried out in the presence of benzoyl peroxide (BPO) as an initiator at 70 °C in benzene under nitrogen atmosphere. Structure and monomer unit composition of the copolymers, obtained from a wide range of monomer feed were determined by elemental analysis. Structural peculiarities of synthesized PAAm, [poly (AAm-alt-CA)] and [poly(AAm-co-CA-co-VA)] were characterized by using Fourier Transform Infrared (FTIR), Uv–vis, 1H-NMR, X-ray diffraction (XRD), elemental analysis, analytical methods (titration methods) and viscometric measurements. |
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