Role of interfacial effects in carbon nanotube/epoxy nanocomposite behavior |
| |
Authors: | Pécastaings G Delhaès P Derré A Saadaoui H Carmona F Cui S |
| |
Affiliation: | Centre de Recherche Paul Pascal-CNRS and Bordeaux I University 115, Avenue du Dr. A. Schweitzer Pessac 33600, France. |
| |
Abstract: | The interfacial effects are critical to understand the nanocomposite behavior based on polymer matrices. These effects are dependent upon the morphology of carbon nanotubes, the type of used polymer and the processing technique. Indeed, we show that the different parameters, as the eventual surfactant use, the ultrasonic treatment and shear mixing have to be carefully examined, in particular, for nanotube dispersion and their possible alignment. A series of multiwalled nanotubes (MWNT) have been mixed with a regular epoxy resin under a controlled way to prepare nanocomposites. The influence of nanotube content is examined through helium bulk density, glass transition temperature of the matrix and direct current electrical conductivity measurements. These results, including the value of the percolation threshold, are analyzed in relationship with the mesostructural organization of these nanotubes, which is observed by standard and conductive probe atomic force microscopy (AFM) measurements. The wrapping effect of the organic matrix along the nanotubes is evidenced and analyzed to get a better understanding of the final composite characteristics, in particular, for eventually reinforcing the matrix without covalent bonding. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|