| 铜试剂对聚氯乙烯的取代反应及其表征 |
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| 引用本文： | 杨文君,王宏,王永祥,管建均,孙正奎. 铜试剂对聚氯乙烯的取代反应及其表征[J]. 青岛科技大学学报(自然科学版), 1996, 0(2) |
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| 作者姓名： | 杨文君 王宏 王永祥 管建均 孙正奎 |
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| 作者单位： | 山东日照港务局 |
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| 摘 要： | 用钢试剂（Ｎ，Ｎ－二乙基二硫代氨基甲酸钠）取代聚氯乙烯上的部分氯原子，可制备出合有多个二乙基二硫代氨基甲酸基的功能高分子。本工作研究取代反应温度、时间、反应物配比及催化剂对取代反应程度的影响，结果表明，当反应温度高于６０℃，时间大于６ｈ，聚氯乙烯与铜试剂的质量比为２／１～３／１时，在丁铜介质中取代反应是定量进行的。即恰当选择反应条件，可有效地调节或控制产物的官能度。
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| 关 键 词： | 聚氯乙烯，功能高分子，有机硫化物，取代反应，化学改性 |
Substitution of Sodium N, N-Diethyldithiocarbamate to Poly (Vinyl Chloride) and Its Characterzation |
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| Tang Wenjun, Wang Hong, Wang Yongxiang, Guan Jianjun. Substitution of Sodium N, N-Diethyldithiocarbamate to Poly (Vinyl Chloride) and Its Characterzation[J]. Journal of Qingdao University of Science and Technology:Natutral Science Edition, 1996, 0(2) |
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| Authors: | Tang Wenjun Wang Hong Wang Yongxiang Guan Jianjun |
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| Affiliation: | Rubber Engineering Department |
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| Abstract: | The partial chloride of PVC was substituted by sodium N, N-- diethyldithio- carbmate (NaSR) so as to prepare functional PVC with diethyldithiopcarbmate groups (PVC- SR ). The effects of the temperature, time, reactant ratio and ctalyst (triethylalmine) on the substitution were studied.The substitution proceeded in basic weight when the substitution temperature was above 60℃,the time above 6 hours and the mass tatio PVC/NaSR=2-3, i. e. the functionality for PVC-SR could be controlled and adjusted effectively by selecting proper reaction conditions. |
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| Keywords: | organosulfide PVC functional polymer chemical modification substitution reaction |
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