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Zinc Titanate Nanofibers for the Detoxification of Chemical Warfare Simulants
Authors:Ramakrishnan Ramaseshan  Seeram Ramakrishna
Affiliation:Nanoscience and Nanotechnology Initiative, National University of Singapore, Singapore 117576, Singapore; Department of Mechanical Engineering, National University of Singapore, Singapore 117576, Singapore; Division of Bioengineering, National University of Singapore, Singapore 119260, Singapore
Abstract:Fabrication of a novel ceramic nanofiber system viz. zinc titanate using the well-known electrospinning technology with polyvinylpyrrolidone as a binder is reported. Use of zinc titanates as reactive sorbents to detoxify chemical warfare agents is hypothesized and proved. The zinc titanate nanofibers are tested against simulants of nerve and mustard agents and show satisfactory destructive activity. The extent of detoxification is measured using GC-MS analysis. The products of reaction of zinc titanate against the simulants are identified and are found to be relatively harmless. The possibility of replacement of conventional-activated carbon by electrospun ceramic nanofibers for face masks and protective clothing is proposed.
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