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低相对分子质量反式-1,4-聚异戊二烯蜡在NR/TPI并用胶中的应用
引用本文:刘玉鹏,杜爱华,姚薇,黄宝琛.低相对分子质量反式-1,4-聚异戊二烯蜡在NR/TPI并用胶中的应用[J].特种橡胶制品,2006,27(6):5-7.
作者姓名:刘玉鹏  杜爱华  姚薇  黄宝琛
作者单位:青岛科技大学,橡塑材料与工程教育部重点实验室,山东,青岛,266042
摘    要:将低相对分子质量反式-1,4-聚异戊二烯蜡(LMTPIW)代替芳烃油用于天然橡胶(NR)和反式-1,4-聚异戊二烯(TPI)并用胶中.研究其对并用胶性能的影响。结果表明,用LMTPIW代替芳烃油用于NR/TPI并用胶中,操作方便,可改善混炼胶的加工性能,混炼胶的焦烧时间延长;提高了硫化胶的拉断伸长率、撕裂强度、屈挠性能;改善了炭黑的分散性;热空气老化性能略有下降。LMTPIW用量在10~15份时,与加入5份芳烃油后的增塑效果相当.屈挠性能可提高2~4倍,胶料的综合性能最佳。

关 键 词:低相对分子质量反式-1  4-聚异戊二烯蜡  芳烃油  天然橡胶  反式-1  4-聚异戊二烯
文章编号:1005-4030(2006)06-0005-03
收稿时间:2006-05-31
修稿时间:2006年5月31日

Application of Low Molecular Weight Trans-1,4-polyisoprene Wax to NR/TPI Blends
LIU Yu-peng,DU Ai-hua,YAO Wei,HUANG Bao-chen.Application of Low Molecular Weight Trans-1,4-polyisoprene Wax to NR/TPI Blends[J].Special Purpose Rubber Products,2006,27(6):5-7.
Authors:LIU Yu-peng  DU Ai-hua  YAO Wei  HUANG Bao-chen
Affiliation:Qingdao University of ,DU Ai-hua ,YAO Wei , HUANG Bao-chen Science and Technology , Qingdao 266042, China
Abstract:The effects of low molecular weight trans-1,4-polyisoprene wax(LMTPIW) on the properties of NR/TPI compounds and vulcanizates were studied,and compared with that of aromatic oil.The results showed that the processibility of NR/TPI blends was improved by using LMTPIW instead of aromatic oil.The scorching time was extended.The elongation at break ,and tear strength of NR/TPI vulcanzates were improved.At the same time the dispersion of carbon black in the NR/TPI compounds containing LMTPIW was also improved. Compared with aromatic oil,LMTPIW could impart good flex fatigue for NR/TPI vulcanizates,but depressed hot air aging properites of NR/TPI vulcanizates lightly at the same time.When the amount of LMTPIW was 10~15phr,the flex crack was improved 2~4 folds.
Keywords:low molecular weight trans 1  4 polyisoprene wax  aromatic oil  NR  trans-1  4 polyisoprene
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