Rapid Method for the Determination of Moisture Content in Biodiesel Using FTIR Spectroscopy |
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Authors: | Mohamed E S Mirghani Nasreldin A Kabbashi Md Zahangir Alam Isam Y Qudsieh Ma’an F R Alkatib |
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Affiliation: | (1) Bioenvironmental Engineering Research Unit (BERU), Department of Biotechnology Engineering, Kulliyyah of Engineering, International Islamic University Malaysia, Gombak, P.O. Box 10, 50728 Kuala Lumpur, Malaysia;(2) Nanotechnology Research Unit, NTRU, Department of Chemical Engineering, College of Engineering, Jazan University, P.O. Box 706, Jazan, 45142, Saudi Arabia; |
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Abstract: | A new, rapid, and direct method was developed for the determination of moisture content in biodiesel produced from various
types of oils using Fourier transform infrared (FTIR) spectroscopy with an attenuated total reflectance (ATR) element. Samples
of biodiesels used in this study were produced using sludge palm oil (SPO). The calibration set was prepared by spiking double-distilled
water into dried biodiesel samples in ratios (w/w) between 0 and 10% moisture. Absorbance values from the wavelength regions
3,700–3,075 and 1,700–1,500 cm−1, and the partial least square (PLS) regression method were used to derive a FTIR spectroscopic calibration model for moisture
content in biodiesel samples. The coefficient of determinations (R
2) for the models was computed by comparing the results obtained from FTIR spectroscopy against the values of the moisture
concentrations (%) determined using the American Oil Chemists’ Society (AOCS) oven method Ca 2d-25. Same comparison was done
using International Union of Pure and Applied Chemistry (IUPAC) distillation method 2.602. R
2 was 0.9793 and 0.9700 using AOCS and IUPAC methods, respectively. The standard error (SE) of calibration was 1.84. The calibration
model was cross validated within the same set of samples, and the standard deviation (SD) of the difference for repeatability
(SDDr) and accuracy (SDDa) of the FTIR method was determined. With its speed and ease of data manipulation, FTIR spectroscopy
is a useful alternative method to other methods for rapid and routine determination of moisture content in biodiesel for quality
control. |
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