Improving bioactivity and durability of yttria-stabilized zirconia |
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Authors: | Miho Nakamura Masahiro Inuzuka Kazuaki Hashimoto Akiko Nagai and Kimihiro Yamashita |
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Affiliation: | (1) Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University, 2-3-10 Kanda-Surugadi, Chiyoda, Tokyo 1010062, Japan;(2) Department of Life and Environmental Science, Chiba Institute of Technology, 2-17-1 Tsudanuma, Narashino, Chiba 2750016, Japan |
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Abstract: | Because of its excellent mechanical properties, yttria-stabilized zirconia is currently used as an orthopedic and dental material.
In this study, we have improved the bioactivity of yttria-stabilized zirconia by a combination of electrical polarization
and chemical treatment. The phase transformation from tetragonal to monoclinic ZrO2 after alkaline treatment was inhibited on positively charged yttria-stabilized zirconia surfaces compared with negatively
charged and conventional surfaces. During polarization, some oxide ions move from the positively charged surface to the negatively
charged surface, leading to an increase in oxygen vacancies on the positive surface and hence greater formation of Zr–OH when
this surface was exposed to alkaline solution. This then reduced the water adsorption at this surface and consequently reduced
the rate of cleavage of Zr–O–Zr bonds. The bioactivity was assessed by immersing the samples in simulated body fluid and evaluating
the growth of apatite on the surfaces. The combination of polarization and alkaline treatment increased the bioactivity in
vitro. |
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