Abstract: | A number of title compounds ( 3a,c,4a—c ) were prepared by cyclization of 5‐aminotetrazolium salts having ketonic substituents ( 1,2 ). The following procedures were applied: a) for 3a, 4a,b : heating of 1a, 2a,b with acetic anhydride‐ base; b) for 3c,4c : heating of 1b,2b in a buffer solution of pH 6.5 (Tschitschibabin reaction). The proclivity for ring closure was more pronounced with the salts 2 . The 6‐unsubstituted representatives 3c and 4c underwent SE‐reactions, the 2H‐isomer 4c being slightly more reactive; this was confirmed by AM1 calculations. The nitroso product 4g exists predominantly as the valence‐isomeric nitrile oxide 6 . |