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溴化N—(3—长链烷氧—2—羟)丙基—N,N,N—三甲基铵的合成及性质
引用本文:张广友,赵淑英.溴化N—(3—长链烷氧—2—羟)丙基—N,N,N—三甲基铵的合成及性质[J].表面活性剂工业,1997(2):15-17,20.
作者姓名:张广友  赵淑英
作者单位:山东建材学院应用化学系!济南市,250022
摘    要:脂肪醇和环氧氯丙烷在相转移条件下反应得到长链烷基缩水甘油醚,以此为原料和三甲胺氢溴酸盐反应得到溴化N-(3-长链烷氧-2-羟)丙基-N,N,N-三甲基铵。其结构通过红外光谱,核磁共振氢谱及元素分析结果得以证实。本文还测定所合成产品的表面张力和临界胶束浓度等。

关 键 词:脂肪醇  表面活性剂  季铵盐  溴化  阳离子型

Synthesis of N-(3-Long Chain Alkyloxy-2-Hydroxy)Propyl-N,N,N,-Trimethylammonium Bromide and Their Properties
Authors:Zhang guangyou
Affiliation:Zhang guangyou et al
Abstract:N-(3-long chain alkyloxy- 2 - hydroxy ) propyl-N, N, N-trimethyl ammonium bromide were synthesized from the reaction of trimethyl ammonium bromide and long chain alkyl glycidyl ether which were prepared from fatty alcohol and epichlorohydrim under a condition of phase transfer catalyst in a yield of 97%.Their structures were confirmed by IR,HNMR and elemental analyses. Surface tension and critical micelle concentration of the products were also determined in this paper.
Keywords:fatty alcohol  surfactant  quaternary ammonium  
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