| 生物质资源合成烷氧基甲基呋喃醚的研究进展 |
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| 引用本文： | 沈鸿波,李兴龙,傅尧. 生物质资源合成烷氧基甲基呋喃醚的研究进展[J]. 生物质化学工程, 2021, 55(4): 43-58. DOI: 10.3969/j.issn.1673-5854.2021.04.007 |
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| 作者姓名： | 沈鸿波 李兴龙 傅尧 |
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| 作者单位： | 中国科学技术大学化学与材料科学学院,安徽合肥230026 |
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| 基金项目： | 中国科学院战略性先导科技专项(XDA21060101);安徽省重大科技项目(18030701157) |
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| 摘 要： | 生物质资源是自然界中唯一的有机碳资源,能用于合成多种高附加值的燃料和化学品.生物质醚类化合物是其中重要的一类衍生物,烷氧基甲基呋喃醚已经应用于柴油和柴油添加剂中,特别是5-乙氧基甲基糠醛(EMF)因其具有能量密度高、毒性低、稳定性好、流动性好等特点而受到广泛关注.本文综述了近年来以5-羟甲基糠醛(HMF)为基本结构的不...
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| 关 键 词： | 有机碳资源 烷氧基甲基呋喃醚 5-羟甲基糠醛 醚化 |
| 收稿时间： | 2020-07-13 |
Recent Advances in Synthesis of Alkoxymethylfuran Ether from Biomass Resources |
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| Hongbo SHEN,Xinglong LI,Yao FU. Recent Advances in Synthesis of Alkoxymethylfuran Ether from Biomass Resources[J]. Biomass Chemical Engineering, 2021, 55(4): 43-58. DOI: 10.3969/j.issn.1673-5854.2021.04.007 |
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| Authors: | Hongbo SHEN Xinglong LI Yao FU |
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| Affiliation: | School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China |
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| Abstract: | Biomass resources are the only organic carbon resources in nature, which can synthesize a variety of high value-added fuels and chemicals. Biomass ethers compounds are one of the most important biomass derivatives. Among them, alkoxymethylfuran ether has been applied to diesel and diesel additives. Especially, 5-(ethoxymethyl)furfural (EMF) has attracted much attention due to its high energy density, low toxicity, good stability and good fluidity. Recent advances in the synthesis of alkoxymethylfuran ether from different biomass materials with 5-(hydroxymethyl)furfural (HMF) as the basic structure were reviewed. The effects of Lewis acid and Brønsted acid on the selectivity of etherification products were discussed. On the basis of summarizing the synthesis methods of alkoxymethylfuran ether, the future development direction of the catalytic system was discussed. |
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| Keywords: | organic carbon resources alkoxymethylfuran ether 5-(hydroxymethyl) furfural (HMF) etherification |
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