Improvement of corrosion resistance of high-velocity oxyfuel-sprayed stainless steel coatings by addition of molybdenum |
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Authors: | Kawakita Jin Kuroda Seiji Fukushima Takeshi Kodama Toshiaki |
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Affiliation: | (1) National Institute for Materials Science 1-2-1, Sengen, Tsukuba, 305-0047 Ibaraki, Japan |
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Abstract: | To improve the marine corrosion resistance of stainless steel coatings fabricated by high-velocity oxyfuel (HVOF) spraying
with a gas shroud attachment, the molybdenum (Mo) content of stainless steel was increased to form coatings with a chemical
composition of Fe balance-18mass%Cr-22mass%Ni-2∼8mass%Mo. These coatings were highly dense, with <0.1 vol.% in porosity, and
less oxidized, with 0.5 mass% in oxygen content at most. The corrosion mechanism and resistance of the coatings were investigated
by electrochemical measurement, chemical analysis, and statistical processing. The general corrosion resistance of the coatings
in 0.5 mol/dm3 sulfuric acid was improved with increases in Mo content, and the corrosion rate could be decreased to 8.8 × 10−2 mg/cm2 per hour (∼1 mm/year) at 8 mass% Mo. The pitting corrosion resistance of the coatings in artificial seawater was improved
with increases in Mo content and was superior to that of the 316L stainless steel coating. The crevice corrosion resistance
of the coatings in artificial seawater was improved and the number of rust spots at 4 mass% Mo was decreased to 38% of that
for the 316L coating. Accordingly, Mo is highly effective in improving the corrosion resistance of the stainless steel coatings
by HVOF spraying. |
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Keywords: | corrosion resistance gas shroud high-velocity oxyfuel molybdenum stainless steel |
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