| 甲酸甲酯水解制备甲酸的工艺研究 |
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| 引用本文： | 李志锋,陈樑,章江洪,宋麟,方智利,李翔宇. 甲酸甲酯水解制备甲酸的工艺研究[J]. 天然气化工, 2002, 27(3): 1-4 |
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| 作者姓名： | 李志锋 陈樑 章江洪 宋麟 方智利 李翔宇 |
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| 作者单位： | 昆明理工大学生物与化学工程学院,云南昆明,650224 |
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| 基金项目： | 云南省省院省校科技合作项目，99YT0 1资助项目 |
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| 摘 要： | 研究了在甲酸为自催化剂的条件下 ,甲酸甲酯与水进行水解反应 ,考察了反应温度、水酯比、反应时间等对水解反应的影响 ,并用正交实验方法确定了水解反应的适宜工艺条件。并确立了甲酸 水二元体系甲酸浓度的校正系数方程及 80kPa压力下的恒沸组成 ,通过常压精馏工艺得到 81%～ 85 % (mass)的甲酸溶液 ,最终建立了甲酸常压跨恒沸点精馏的工艺。
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| 关 键 词： | 甲酸 甲酸甲酯 水解 精馏 |
| 文章编号： | 1001-9219(2002)03-01-04 |
| 修稿时间： | 2002-01-25 |
Study on the technology of preparing formic acid by hydrolysis of methyl formate |
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| LI Zhi feng,CHEN Liang,ZHANG Jiang hong,SONG Lin,FANG Zhi li,LI Xiang yu. Study on the technology of preparing formic acid by hydrolysis of methyl formate[J]. Natural Gas Chemical Industry, 2002, 27(3): 1-4 |
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| Authors: | LI Zhi feng CHEN Liang ZHANG Jiang hong SONG Lin FANG Zhi li LI Xiang yu |
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| Abstract: | The preparation process of formic acid (FA) by hydrolysis of methyl formate (MF) and distillation of FA were studied. The influences of temperature, water/MF molecular ratio and reaction time on hydrolysis of MF were observed and the best process conditions for hydrolysis of MF were determined by orthogonol experiments. The rectifying equation of MA concentration for FA H 2O system was established, and the constant boiling compositions for the same system was also measured. 81%～85% formic acid solution was prepared by atmospheric rectification, and, finally, a MA rectifying process across constant boiling point was established. |
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| Keywords: | formic acid methyl formate hydrolysis rectification |
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