| 稀土助剂促进的Rh/SiO_2催化剂上CO+H_2反应合成C_2含氧化合物的研究 |
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| 引用本文： | 张伟,罗洪原,周焕文,林培滋,黄世煜,吴治华,林励吾. 稀土助剂促进的Rh/SiO_2催化剂上CO+H_2反应合成C_2含氧化合物的研究[J]. 天然气化工, 1998, 0(6) |
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| 作者姓名： | 张伟 罗洪原 周焕文 林培滋 黄世煜 吴治华 林励吾 |
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| 作者单位： | 中国科学院大连化学物理研究所国家重点实验室 |
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| 摘 要： | 研究了稀土促进剂对ＣＯ＋Ｈ２合成二碳含氧化合物的Ｒｈ／ＳｉＯ２催化剂反应性能的影响，并用ＴＰＲ、Ｈ２－ＴＰＤ、ＣＯ和Ｈ２化学吸附方法进行了表征
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| 关 键 词： | 铑；稀土；乙醇；乙酸；含氧化合物；合成气 |
Study of CO H 2 reaction for synthesis of C 2 oxygenates over Rh/SiO 2 catalysts promoted by rare earth compounds |
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| Zhang Wei,Luo Hongyuan Zhou Huanwen,Lin Peizi Huang Shiyu,Wu Zhihua,Lin Liwu. Study of CO H 2 reaction for synthesis of C 2 oxygenates over Rh/SiO 2 catalysts promoted by rare earth compounds[J]. Natural Gas Chemical Industry, 1998, 0(6) |
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| Authors: | Zhang Wei Luo Hongyuan Zhou Huanwen Lin Peizi Huang Shiyu Wu Zhihua Lin Liwu |
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| Abstract: | Rh catalysts with rare earth elements as promoters were evaluated by CO H 2 reaction for synthesis of C 2 oxygenates and characterized by TPR,H 2 TPD and uptakes of CO and hydrogen. The results indicated that addition of rare earth elements obviously improved the activity and selectivity of the catalysts for synthesis of C 2 oxygenates from CO and H 2.The increase of activity and selectivity to C 2 oxygenates of the catalysts were correlated with the results of characterization. |
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| Keywords: | Abstract: rhodium rare earth ethanol acetic acid C 2 oxygenate syngas |
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