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Use of the phenanthrene-based lithium initiator in the anionic polymerization of methyl methacrylate |
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| Authors: | Z Hruska B Vuillemin G Riess |
| Affiliation: | (1) Ecole Nationale Supérieure de Chimie, F-68200 Mulhouse, France;(2) Present address: Central Laboratory, Solvay S.A., rue de Ransbeek 310, B-1120 Brussels, Belgium;(3) Present address: Dept. Polymères, Groupement de Recherche de Lacq, F-64170 Artix, France |
| Abstract: | Summary A series of poly (methyl methacrylate) PMMA polymers with low polydispersity was synthesized anionically using sterically hindered (1-(9-phenanthryl)-1-phenyl-3-methylpentyl)lithium as an initiator. Results of absorption spectroscopy and gelpermeation chromatography (GPC) analyses were used to discuss the initiator efficiency. |
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