Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint |
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Authors: | Rebelo Luís Paulo N Lopes José N Canongia Esperança José M S S Guedes Henrique J R Łachwa Joanna Najdanovic-Visak Vesna Visak Zoran P |
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Affiliation: | Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Av. República, Apartado 127, 2780-901 Oeiras, Portugal. luis.rebelo@itqb.unl.pt |
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Abstract: | The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid-liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions. |
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