| 新型以无机物为主的免增湿复合质子交换膜 |
| |
| 引用本文： | 索进平,崔崑,钱晓良,肖建中. 新型以无机物为主的免增湿复合质子交换膜[J]. 复合材料学报, 2004, 21(1): 23-27 |
| |
| 作者姓名： | 索进平 崔崑 钱晓良 肖建中 |
| |
| 作者单位： | 华中科技大学,塑性成形模拟及模具技术国家重点实验室,武汉,430074 |
| |
| 基金项目： | 国家自然科学基金(29876015) |
| |
| 摘 要： | 研究一种新型免增湿无机-有机复合质子交换膜,这种复合质子交换膜中的无机物含量达60%以上,且其中部分无机颗粒交联成为无机大分子,具有良好的耐酸稳定性。化学结合水到120℃左右才分解,在80℃干燥30min后,在潮湿的空气中(RH90%)可自动吸湿恢复原重。在干燥空气(相对湿度<40%)中具有良好的导电能力,室温电导率达1.14×10-2S/cm,在60℃时达到2.81×10-2S/cm。
|
| 关 键 词： | 燃料电池 复合质子交换膜 增湿 |
| 文章编号： | 1000-3851(2004)01-0023-05 |
| 收稿时间： | 2002-11-28 |
| 修稿时间： | 2003-03-13 |
NOVEL UNHUMIDIFIED COMPOSITE PROTON EXCHANGE MEMBRANE DOMINATED BY INORGANIC MATERIALS |
| |
| SUO Jinping,CUI Kun,QIAN Xiaoliang,SHANG Jianzhong. NOVEL UNHUMIDIFIED COMPOSITE PROTON EXCHANGE MEMBRANE DOMINATED BY INORGANIC MATERIALS[J]. Acta Materiae Compositae Sinica, 2004, 21(1): 23-27 |
| |
| Authors: | SUO Jinping CUI Kun QIAN Xiaoliang SHANG Jianzhong |
| |
| Affiliation: | State Key Laboratory of Plastic Forming Modeling &|Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, China |
| |
| Abstract: | A new inorganic and organic composite membrane with above 60% inorganic materials was developed in this paper. The composite membrane possessed good sulfuric acid resistance because part of inorganic materials crosslinked in drying. After being dried at 80℃ for 30min, the membrane could restore its original weight in moisture air, and the chemically combined water in the membrane dissolved until to 120℃,therefore the membrane showed excellent proton conductivity even in dry air with relative humidity below 40%. The conductivity was 1.14×10-2 S/cm at room temperature and increased to 2.81×10-2S/cm at 60℃. Without any humidification, the power density of this composite membrane was twice that of Nafion117 at room temperature. |
| |
| Keywords: | fuel cell composite proton exchange membrane humidification |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《复合材料学报》浏览原始摘要信息 |
|
点击此处可从《复合材料学报》下载免费的PDF全文 |
|
