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Thermodynamic evaluation of phase equilibria in the CaCl2-MgCl2-CaF2-MgF2 system |
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| Authors: | A D Pelton P K Talley R A Sharma |
| Affiliation: | 1. Centre de Recherche en Calcul Thermochimique, Ecole Polytechnique, P.O. Box 6079, H3C 3A7, Station A Montréal, Quebéc, Canada 2. Physical Chemistry Department, GM Research Laboratories, 12 Mile and Mound Rd., Box 9055, 48090-9055, Warren, Michigan |
| Abstract: | The phase diagram of the CaCl2-CaF2-MgCl2-MgF2 reciprocal ternary system was calculated thermodynamically from available data on the common-ion binary subsystems and from available data on the CaCl2-MgF2 join. This join is very nearly quasibinary and divides the system into two quasiternary systems: the CaCl2-MgF2-CaF2 system with a ternary eutectic calculated at 724 +-5 °C and the CaC2-MgF2-MgCl2 system with a ternary eutectic calculated at 561 +-5 °C. |
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