6,7-甲氧基香豆素冠醚双功能化杯【4】芳烃的合成与表征 |
| |
引用本文: | 张德华,张晓燕,吕鉴泉.6,7-甲氧基香豆素冠醚双功能化杯【4】芳烃的合成与表征[J].化工中间体,2008(6):1-3. |
| |
作者姓名: | 张德华 张晓燕 吕鉴泉 |
| |
作者单位: | 1. 湖北师范学院化学与环境工程学院,黄石,435002 2. 黄石理工学院数理学院,湖北,黄石,435002 3. 湖北师范学院生化分析技术湖北省重点实验室,黄石,435002 |
| |
基金项目: | 湖北师范学院研究生启动基金
,
教育部科学技术基金
,
湖北省教育厅重点项目 |
| |
摘 要: | 以对叔丁基杯4]芳烃为原料,经碱催化两步合成了26,28-二(6,7-二甲氧基香豆素-4-亚甲基)-5,11,17,23-四叔丁基杯4]芳烃-25,27-冠-6,产物经IR、^1H NMR表征和元素分析表征,该衍生物为锥形结构并与设计思想一致。
|
关 键 词: | 合成 杯 芳烃 6 7-甲氧基香豆素 冠醚 |
Synthesis and Characterization of Difunctionalized Calix[4]Arene Containing 6,7-Dimethoxycoumarin and Crown Ether |
| |
Authors: | ZHANG De-hua ZHANG xiao-yan LU Jian-quan |
| |
Affiliation: | ZHANG De-hua, ZHANG xiao-yan, LU Jian-quan (1. Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002;2. School of Mathemtics and Physics, Huangshi Institute of Technology,435002;3. Hubei Key Laboratory of Bioanalytical Technology' Hubei Normal University, Huangshi ,435002) |
| |
Abstract: | A novel calix 4]arene, 26,28-di (4-bromomethyl-6,7-dimethoxycoumarin)-5,11,17,23-tetrabutylcalix 4]arene-25,27-crown-6, was synthesized and characte-rized The structure were confirmed by IR,^1H NMR and Elemental analysis. The results showed that the derivative backbone adopts the cone conformation. |
| |
Keywords: | synthesis calix arene 6 7-dimethoxycoumarin crown ether |
本文献已被 维普 万方数据 等数据库收录! |
|