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碲对正极板栅合金结构与性能的影响
引用本文:郭文显,陈红雨. 碲对正极板栅合金结构与性能的影响[J]. 蓄电池, 2010, 47(2): 51-54
作者姓名:郭文显  陈红雨
作者单位:1. 广州番禺职业技术学院珠宝学院,广东,广州,511483
2. 华南师范大学化学与环境学院,广东,广州,510006
摘    要:在偏光显微镜下观察铅碲二元合金(Pb—Te)的组织结构。高温恒电流腐蚀后,利用扫描电镜分析Pb—Te合金的腐蚀形貌。把各合金制成电极,用循环伏安(CV)、开路电位(OCP)等方法研究了纯铅和Pb—Te合金作为正极的电化学性能。结构实验表明,掺入适量的碲可以细化铅合金的晶粒。通过观察Pb—Te合金的腐蚀形貌,发现适量的碲可以提高板栅合金的耐腐蚀性能;电化学实验表明掺碲还会抑制二氧化铅的生长,从而减轻了合金的腐蚀。

关 键 词:铅酸蓄电池  正极板栅  铅碲合金

Influence of tellurium on the structure and properties of positive grid alloys
GUO Wen-xian,CHEN Hong-yu. Influence of tellurium on the structure and properties of positive grid alloys[J]. Chinese Labat Man, 2010, 47(2): 51-54
Authors:GUO Wen-xian  CHEN Hong-yu
Affiliation:GUO Wen-xian1,CHEN Hong-yu2(1.Jewelry Institute of Guangzhou Panyu Polytechnic,Guangzhou Guangdong,511483,2.School of Chemistry , Environment,South China Normal University,Guangzhou,Guangdong,510006)
Abstract:The microstructure of Pb-Te binary alloys was observed using a polarizing microscope.The morphology of the corrosion sections of Pb and Pb-Te alloys were analyzed by scanning electron micro-scope(SEM) following the corrosion test.The electrochemical properties of Pb-Te alloys in sulfuric acid solution were investigated by cyclic voltammetry(CV),open circuit potential(OCP).The results indi-cate that the introduction of tellurium results in grain refinement,increased corrosion resistance for posi-tive grid al...
Keywords:lead-acid battery  positive grid alloy  lead tellurium alloy  
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