MIL-101 Supported Polyoxometalates: Synthesis,Characterization, and Catalytic Applications in Selective Liquid-Phase Oxidation |
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| Authors: | Nataliya V. Maksimchuk Oxana A. Kholdeeva Konstantin A. Kovalenko Vladimir P. Fedin |
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| Affiliation: | 1. Boreskov Institute of Catalysis, Lavrentiev Avenue 5, Novosibirsk 630090, Russia phone: +7 (0)383 3269433 fax: +7 (0)383 3309573;2. Nikolaev Institute of Inorganic Chemistry, Lavrentiev Avenue 3, Novosibirsk 630090, Russia |
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| Abstract: | In this short review paper, we survey our recent achievements in the preparation of heterogeneous catalysts via incorporation of polyoxometalates (POMs) within cages of the mesoporous coordination polymer MIL-101, their physicochemical characterization, and application for liquid-phase selective oxidation of organic compounds with green oxidants — O2 and aqueous H2O2. Special attention is paid to analyze a manifestation of confinement effects and to address the issues of catalytic activity and selectivity after immobilization and after recycling, catalyst resistance to POM leaching, and the nature of catalysis. The scope and limitations of POM/MIL-101 catalysts are discussed. |
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| Keywords: | heterogeneous catalysis metal-organic framework MIL-101 selective oxidation supported polyoxometalate |
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