Asymmetric Intermolecular Mizoroki-Heck Reaction: From Phosphine/Phosphinite-Nitrogen to Phosphite-Nitrogen Ligands |
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| Authors: | Montserrat Diéguez Oscar Pàmies |
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| Affiliation: | Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/ Marcel⋅lí Domingo s/n, 43007 Tarragona (Spain), Fax: (+34)-977559563 |
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| Abstract: | This review discusses the latest developments in ligand design for the Pd-catalyzed asymmetric intermolecular Mizoroki-Heck reaction, from the successful phosphine/phosphinite-nitrogen ligands to the recently reported phosphite-nitrogen ligands. The presence of a biaryl phosphite group offers several advantages as a ligand scaffold for this process. |
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| Keywords: | asymmetric catalysis Heck reaction palladium P N ligands |
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