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使用LiFePO_4-LiMn_2O_4混合正极的锂离子电池的性能
引用本文:郑立娟,卢星河,崔燕.使用LiFePO_4-LiMn_2O_4混合正极的锂离子电池的性能[J].电池,2010,40(1).
作者姓名:郑立娟  卢星河  崔燕
作者单位:河北工业大学化工学院,天津,300130;河北工业大学化工学院,天津,300130;河北工程大学理学院,河北,邯郸,056038;广州市鹏辉电池有限公司,广东,广州,511483
摘    要:将LiFePO4和Li Mn2O4按78∶9的质量比混合,并用作锂离子电池正极材料。使用该混合正极的14500型电池适宜的充放电电压范围为4.20~2.50 V,在常温下以1.0C循环250次,容量保持率为87.47%;在60℃下以1.0C循环12次,容量保持率为84.62%。电池以100%SOC在60℃下贮存7 d后,容量保持率为82.50%,容量恢复率为89.01%。

关 键 词:锂离子电池  正极材料  混合正极  LiFePO_4  LiMn_2O_4

The performance of Li-ion battery using LiFePO_4-LiMn_2O_4 mixed cathode
ZHENG Li-juan,LU Xing-he,CUI Yan.The performance of Li-ion battery using LiFePO_4-LiMn_2O_4 mixed cathode[J].Battery Bimonthly,2010,40(1).
Authors:ZHENG Li-juan  LU Xing-he  CUI Yan
Abstract:LiFePO_4 and LiMn_2O_4 was mixed with the mass ratio of 78:9 and used as cathode material of Li-ion battery. The pro-per charge-discharge voltage range of 14500 type battery using the mixed cathode was 4.20~2.50 V. When 1.0 C cycle at room temperature,the capacity retention rate was 87.47% after 250 cycles,when 1.0 C cycle at 60 ℃,the capacity retention rate was 84.62% after 12 cycles. When the battery was stored 7 d at 60 ℃ with 100% SOC,the capacity retention rate was 82.50%,the capacity recovery rate was 89.01%.
Keywords:LiFePO_4  LiMn_2O_4  Li-ion battery  cathode material  mixed cathode  LiFePO_4  LiMn_2O_4
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