| 硅钨酸催化合成柠檬酸三丁酯的研究 |
| |
| 引用本文： | 吴茂祥,高冬寿.硅钨酸催化合成柠檬酸三丁酯的研究[J].精细石油化工,1999(6):23-25. |
| |
| 作者姓名： | 吴茂祥 高冬寿 |
| |
| 作者单位： | 中国科学院福建物质结构研究所!福州，350002，中国科学院福建物质结构研究所!福州，350002，中国科学院福建物质结构研究所!福州，350002，中国科学院福建物质结构研究所!福州，350002，中国科学院福建物质结构研究所!福州，350002，中国科学院福建物质结构研究所!福州，350002 |
| |
| 摘 要： | 考察了催化剂用量、酸醇比、反应时间、反应温度对硅钨酸均相催化酯化合成柠檬酸三丁酯反应的影响 ,对合成的产品进行了红外光谱分析及纯度的测定。在柠檬酸用量为 2 1 g,正丁醇为 55m L ,催化剂量为 0 .3 g,反应时间 2 .5h,反应温度 1 4 5℃的优化条件下 ,柠檬酸三丁酯收率为 98.3 %。
|
| 关 键 词： | 增塑剂 柠檬酸三丁酯 酯化 杂多酸 |
THE SYNTHESIS OF TRIBUTYL CITRATE CATALYZED BY TUNGSTOSILICIC ACID |
| |
| Wu Maoxiang,Gao Dongshou,Li Ding,Luo Junhua,Wang Yanming and Chen Changzhang.THE SYNTHESIS OF TRIBUTYL CITRATE CATALYZED BY TUNGSTOSILICIC ACID[J].Speciality Petrochemicals,1999(6):23-25. |
| |
| Authors: | Wu Maoxiang Gao Dongshou Li Ding Luo Junhua Wang Yanming and Chen Changzhang |
| |
| Abstract: | Homogenous catalytic synthesis of tributyl citrate catalyzed by tungstosilicic acid was studied. The effects of reaction conditions were discussed, such as the quantity of catalyst, the ratio of the reactants, reaction time and the reaction temperature. The product was detected by IR spectra. The most suitable conditions for the reaction were as follows: citrate 21 g, butyl alcohol 55 mL, tungstosilicic acid 0.3 g, reaction time 2.5 h, reaction temperature 145 ℃, the yield of tributyl citrate was over 98.3%. |
| |
| Keywords: | plasticizer tributyl citrate esterification heteropolyacid |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
