High rate performance of a lithium polymer battery using a novel ionic liquid polymer composite |
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Authors: | Takaya Sato Shoko Marukane Takuya Narutomi Tadayoshi Akao |
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Affiliation: | 1. Tsuruoka National College of Technology, Department of Material Engineering, 104 Sawada, Inooka, Tsuruoka 997-8511, Japan;2. Enerstruct Incorporated, KSP BLDG R&D C-335, Sakado, Takatsuku, Kawasaki, Kanagawa 213-0012, Japan |
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Abstract: | We present a new design of a lithium gel-polymer battery, fabricated with a (LILP) composite consisting of a lithium salt dissolved in an ionic liquid (binary Li-IL) and an ultra high molecular weight ionic liquid polymer (ILP). This polymer, with a Mw of over a million, was prepared by the bulk radical polymerization of a novel ionic liquid monomer, N,N-diethyl-N-(2-methacryloylethyl)-N-methylammonium bis(trifluoromethylsulfonyl)imide (DEMM-TFSI). The polymer could form a binary Li-IL solid at a concentration of only 5 wt%. We selected high power-active electrode materials, and combined them with the LILP system. The demonstration vapor-free cell had a higher discharge performance than a conventional lithium polymer battery: at 40 °C, it retained 83% of its discharge capacity at a 3 C current, and relatively good cycle performance. This is the first report of to knowledge that a lithium ion cell with a LILP system performed, in terms of cell performance and cycle durability, at a level of practical utility. |
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Keywords: | Lithium polymer battery Polymerizable ionic liquids Ultra high molecular weight polymer Gel Rate performance |
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